Sure thing. I'm using C# and this example shows how to create a multiline tooltip when the user hovers over the chart area.
// Get a reference to the map area you want the tooltip to be associated with
MapArea _chartMap = webchart.ImageAreas.GetByName("ChartData");
// set the tooltip message to whatever makes sense for your implementation
// I've highlighted the newline characters in orange for clarity
_chartMap.Tooltip = string.Format("YTD Excellence {0}\nYTD Overall {1}\nFeb Excellence {2}\nFeb Overall {3}",
ytdExcellence.ToString("P"),
ytdOverall.ToString("P"),
monthlyExcellence.ToString("P"),
(monthlyOverall.ToString("P")
);
Please note that the newline escape character in VB.Net is quite probably different than in C#. Unfortunately, I don't know what the character is; but I would try what I've outlined first. Also, this example uses the string.format function to make a string containing variable information; but this could have been done just as easily without it.